Project description:In order to explore the influence of electrode spacing on the performance of the enhanced bioretention system, four bioretention cells with microbial fuel cell (BRC-MFC) systems with different electrode spacing were designed, and the effect of electrode spacing on system performance was revealed by analysing its water treatment capacity and electricity production efficiency. The results showed that BRC-MFC had good water treatment capacity and could produce electricity simultaneously. Compared with other BRC-MFC systems with spacing, the BRC3 system (with an electrode spacing of 30 cm) had significant water treatment capacity under different organic loads, especially under high organic load (C/N = 10) operation, COD removal rate was as high as 98.49%, NH4+-N removal rate was as high as 97%, and it had a higher output voltage of 170.46 ± 6.17 mV. It could be seen that proper electrode spacing can effectively improve the water treatment capacity of the BRC-MFC system. This study provided a feasible method for improving the performance of the BRC-MFC system, and revealed the relevant mechanism. A proper electrode spacing with sufficient carbon sources could effectively improve the water treatment capacity of the BRC-MFC system.
Project description:Stormwater rapidly moves trace organic contaminants (TrOCs) from the built environment to the aquatic environment. Bioretention cells reduce loadings of some TrOCs, but they struggle with hydrophilic compounds. Herein, we assessed the potential to enhance TrOC removal via changes in bioretention system design by simulating the fate of seven high-priority stormwater TrOCs (e.g., PFOA, 6PPD-quinone, PAHs) with log KOC values between -1.5 and 6.74 in a bioretention cell. We evaluated eight design and management interventions for three illustrative use cases representing a highway, a residential area, and an airport. We suggest two metrics of performance: mass advected to the sewer network, which poses an acute risk to aquatic ecosystems, and total mass advected from the system, which poses a longer-term risk for persistent compounds. The optimized designs for each use case reduced effluent loadings of all but the most polar compound (PFOA) to <5% of influent mass. Our results suggest that having the largest possible system area allowed bioretention systems to provide benefits during larger events, which improved performance for all compounds. To improve performance for the most hydrophilic TrOCs, an amendment like biochar was necessary; field-scale research is needed to confirm this result. Our results showed that changing the design of bioretention systems can allow them to effectively capture TrOCs with a wide range of physicochemical properties, protecting human health and aquatic species from chemical impacts.
Project description:Bioretention, also known as rain garden, allows stormwater to soak into the ground through a soil-based medium, leading to removal of particulate and dissolved pollutants and reduced peak flows. Although soil organic matter (SOM) is efficient at sorbing many pollutants, amending the bioretention medium with highly effective adsorbents has been proposed to optimize pollutant removal and extend bioretention lifetime. The aim of this research was to investigate whether soil amended with activated carbon produced from sewage sludge increases the efficiency to remove hydrophobic organic compounds frequently detected in stormwater, compared to non-amended soil. Three lab-scale columns (520 cm3) were packed with soil (bulk density 1.22 g/cm3); activated carbon (0.5% w/w) was added to two of the columns. During 28 days, synthetic stormwater-ultrapure water spiked with seven hydrophobic organic pollutants and dissolved organic matter in the form of humic acids-was passed through the column beds using upward flow (45 mm/h). Pollutant concentrations in effluent water (collected every 12 h) and polluted soils, as well as desorbed amounts of pollutants from soils were determined using GC-MS. Compared to SOM, the activated carbon exhibited a significantly higher adsorption capacity for tested pollutants. The amended soil was most efficient for removing moderately hydrophobic compounds (log K ow 4.0-4.4): as little as 0.5% (w/w), carbon addition may extend bioretention medium lifetime by approximately 10-20 years before saturation of these pollutants occurs. The column tests also indicated that released SOM sorb onto activated carbon, which may lead to early saturation of sorption sites on the carbon surface. The desorption test revealed that the pollutants are generally strongly sorbed to the soil particles, indicating low bioavailability and limited biodegradation.
Project description:The dissolved metal adsorption and association was determined for ten different filter materials recommended and/or implemented in bioretention facilities. Batch adsorption and batch kinetic experiments were performed at lab-scale using both single and multi-metal solutions. Metal strengths and association were determined by sequential extraction analysis. All materials adsorbed metals and 90% of adsorption occurred within 1 h. However, as metal solutions became more complex, adsorption behavior changed. Generally, filter materials classified as sand with a naturally high pH, relatively low organic matter (OM) content and large specific surface area seem to be good choices for removing dissolved metals. Additionally, a chalk additive might improve metal adsorption whereas biochar did not significantly improve metal retention and may be an unwanted (due to degradation over time) extra source of OM. Regardless of filter material, metals primarily adsorbed to the exchangeable form which indicates that metal adsorption might not be permanent, but rather substantially reversible in some cases. More research is needed to assess whether dissolved metals adsorbed in filter materials of bioretention systems pose a delayed threat instead of an immediate threat. Finally, the authors strongly recommend filter materials intended for stormwater bioretention facilities to be tested prior to implementation.
Project description:Green stormwater infrastructure like bioretention can reduce stormwater runoff volumes and trap sediments and pollutants. However, bioretention soil media can be both a sink and source of phosphorus (P). We investigated the potential tradeoff between hydraulic conductivity and P sorption capacity in drinking water treatment residuals (DWTRs), with implications for bioretention media design. Batch isotherm and flow-through column experiments were used to quantify the maximum P sorption capacity (Smax) and rate of P sorption for three DWTR sources. Smax values varied greatly among DWTR sources and methodologies, which has implications for regulatory standards. We also conducted a large column experiment to determine the hydraulic and P removal effects of amending bioretention media with solid and mixed layers of DWTRs. When applied to bioretention media, the impact of DWTRs on hydraulic conductivity and P removal depended on layering strategy. Although DWTR addition in solid and mixed layer designs improved P removal, the solid layer restricted water flow and exhibited incomplete P removal, while the mixed layer had no effect on flow and removed ~100% of P inputs. We recommend that DWTRs be mixed with sand in bioretention media to simultaneously achieve stormwater drainage and P reduction goals in green stormwater infrastructure.
Project description:Excessive phosphorus (P) contributes to eutrophication by degrading water quality and limiting human use of water resources. Identifying economic and convenient methods to control soluble reactive phosphorus (SRP) pollution in urban runoff is the key point of rainwater management strategies. Through three series of different tests involving influencing factors, continuous operation and intermittent operation, this study explored the purification effects of bioretention tanks under different experimental conditions, it included nine intermittent tests, single field continuous test with three groups of different fillers (Fly ash mixed with sand, Blast furnace slag, and Soil), and eight intermittent tests with single filler (Blast furnace slag mixed with sand). Among the three filler combinations studied, the filler with fly ash mixed with sand achieved the best pollution reduction efficiency. The setting of the submerged zone exerted minimal influence on the P removal of the three filler combinations. An extension of the dry period slightly promoted the P purification effect. The combination of fly ash mixed with sand demonstrated a positive purification effect on SRP during short- or long-term simulated rainfall duration. Blast furnace slag also presented a positive purification effect in the short term, although its continuous purification effect on SRP was poor in the long term. The purification abilities of soil in the short and long terms were weak. Under intermittent operations across different seasons, SRP removal was unstable, and effluent concentration processes were different. The purification effect of the bioretention system on SRP was predicted through partial least squares regression (PLS) modeling analysis. The event mean concentration removal of SRP was positively related to the adsorption capacity of filler and rainfall interval time and negatively related to submerged zones, influent concentration and volume.
Project description:Drinking water treatment residuals (DWTRs) are a promising media amendment for enhancing phosphorus (P) removal in bioretention systems, but substantial removal of dissolved P by DWTRs has not been demonstrated in field bioretention experiments. We investigated the capacity of a non-amended control media (Control) and a DWTR-amended treatment media (DWTR) to remove soluble reactive P (SRP), dissolved organic P (DOP), particulate P (PP), and total P (TP) from stormwater in a two-year roadside bioretention experiment. Significant reductions m SRP, PP and TP concentrations and loads were observed in both the Control and DWTR media. However, the P removal efficiency of the DWTR cells were greater than those of the Control cells for all P species, particularly during the second monitoring season as P sorption complexes likely began to saturate in the Control cells. The difference in P removal efficiency between the Control and DWTR cells was greatest during large storm events, which transported the majority of dissolved P loads in this study. We also investigated the potential for DWTRs to restrict water flow through bioretention media or leach heavy metals. The DWTRs used in this study did not affect the hydraulic performance of the bioretention cells and no significant evidence of heavy metal leaching was observed during the study period. Contrasting these results with past studies highlights the importance of media design in bioretention system performance and suggests that DWTRs can effectively capture and retain P without affecting system hydraulics if properly incorporated into bioretention media.