Preparation of Porous Ti/RuO₂-IrO₂@Pt, Ti/RuO₂-TiO₂@Pt and Ti/Y₂O₃-RuO₂-TiO₂@Pt Anodes for Efficient Electrocatalytic Decomposition of Tetracycline.

ABSTRACT: Electrocatalytic oxidation (ECO) has attracted attention because of its high efficiency and environmental friendliness in water treatment. The preparation of anodes with high catalytic activity and long service lifetimes is a core part of electrocatalytic oxidation technology. Here, porous Ti/RuO₂-IrO₂@Pt, Ti/RuO₂-TiO₂@Pt, and Ti/Y₂O₃-RuO₂-TiO₂@Pt anodes were fabricated by means of modified micro-emulsion and vacuum impregnation methods with high porosity titanium plates as substrates. The scanning electron microscopy (SEM) images showed that RuO₂-IrO₂@Pt, RuO₂-TiO₂@Pt, and Y₂O₃-RuO₂-TiO₂@Pt nanoparticles were coated on the inner surface of the as-prepared anodes to form the active layer. Electrochemical analysis revealed that the high porosity substrate could result in a large electrochemically active area, and a long service life (60 h at 2 A cm^-2 current density, 1 mol L^-1 H₂SO₄ as the electrolyte, and 40 °C). The degradation experiments conducted on tetracycline hydrochloride (TC) showed that the porous Ti/Y₂O₃-RuO₂-TiO₂@Pt had the highest degradation efficiency for tetracycline, reaching 100% removal in 10 min with the lowest energy consumption of 167 kWh kg^-1 TOC. The reaction was consistent with the pseudo-primary kinetics results with a k value of 0.5480 mol L^-1 s^-1, which was 16 times higher than that of the commercial Ti/RuO₂-IrO₂ electrode. The fluorospectrophotometry studies verified that the degradation and mineralization of tetracycline were mainly ascribed to the •OH generated in the electrocatalytic oxidation process. This study thus presents a series of alternative anodes for future industrial wastewater treatment.

SUBMITTER: Zhu Y 

PROVIDER: S-EPMC10004508 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature