Si Doping-Induced Electronic Structure Regulation of Single-Atom Fe Sites for Boosted CO₂ Electroreduction at Low Overpotentials.

ABSTRACT: Transition metal-based single-atom catalysts (TM-SACs) are promising alternatives to Au- and Ag-based electrocatalysts for CO production through CO₂ reduction reaction. However, developing TM-SACs with high activity and selectivity at low overpotentials is challenging. Herein, a novel Fe-based SAC with Si doping (Fe-N-C-Si) was prepared, which shows a record-high electrocatalytic performance toward the CO₂-to-CO conversion with exceptional current density (>350.0 mA cm^-2) and ~100% Faradaic efficiency (FE) at the overpotential of <400 mV, far superior to the reported Fe-based SACs. Further assembling Fe-N-C-Si as the cathode in a rechargeable Zn-CO₂ battery delivers an outstanding performance with a maximal power density of 2.44 mW cm^-2

SUBMITTER: Cao C 

PROVIDER: S-EPMC10017332 | biostudies-literature | 2023

REPOSITORIES: biostudies-literature