Limits to the strain engineering of layered square-planar nickelate thin films.

ABSTRACT: The layered square-planar nickelates, Nd_n+1Ni_nO_2n+2, are an appealing system to tune the electronic properties of square-planar nickelates via dimensionality; indeed, superconductivity was recently observed in Nd₆Ni₅O₁₂ thin films. Here, we investigate the role of epitaxial strain in the competing requirements for the synthesis of the n = 3 Ruddlesden-Popper compound, Nd₄Ni₃O₁₀, and subsequent reduction to the square-planar phase, Nd₄Ni₃O₈. We synthesize our highest quality Nd₄Ni₃O₁₀ films under compressive strain on LaAlO₃ (001), while Nd₄Ni₃O₁₀ on NdGaO₃ (110) exhibits te

SUBMITTER: Ferenc Segedin D 

PROVIDER: S-EPMC10020545 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature