E-selective Semi-hydrogenation of Alkynes under Mild Conditions by a Diruthenium Hydride Complex.

ABSTRACT: The synthesis, characterization and catalytic activity of a new class of diruthenium hydrido carbonyl complexes bound to the ^tBu PNNP expanded pincer ligand is described. Reacting ^tBu PNNP with two equiv of RuHCl(PPh₃ )₃ (CO) at 140 °C produces an insoluble air-stable complex, which was structurally characterized as [Ru₂ (^tBu PNNP)H(μ-H)Cl(μ-Cl)(CO)₂ ] (1) using solid-state NMR, IR and X-ray absorption spectroscopies and follow-up reactivity. A reaction with KOtBu results in deprotonation of a methylene linker to produce [Ru₂ (^tBu PNNP^* )H(μ-H)(μ-OtBu)(CO)₂ ] (3) featuring a partially dearomatized naphthyridine core. This enables metal-ligand cooperative activation of H<

SUBMITTER: van Beek CB 

PROVIDER: S-EPMC10092327 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature