Outstanding Electrochemical Performance of Ni-Rich Concentration-Gradient Cathode Material LiNi_0.9Co_0.083Mn_0.017O₂ for Lithium-Ion Batteries.

ABSTRACT: The full-concentrationgradient LiNi_0.9Co_0.083Mn_0.017O₂ (CG-LNCM), consisting of core Ni-rich LiNi_0.93Co_0.07O₂, transition zone LiNi_1-x-yCo_xMn_yO_2, and outmost shell LiNi_1/3Co_1/3Mn_1/3O₂ was prepared by a facile co-precipitation method and high-temperature calcination. CG-LNCM was then investigated with an X-ray diffractometer, ascanning electron microscope, a transmission electron microscope, and electrochemical measurements. The results demonstrate that CG-LNCM has a lower cation mixing of Li⁺ and Ni²⁺ and larger Li⁺ diffusion coefficients than concentration-constant LiNi_0.9Co_0.083Mn_0.017O₂ (CC-LNCM). CG-LNCM presents a higher capacity and a better rate of capability and cyclability than CC-LNCM. CG-LNCM and CC-LNCM show initial discharge capacities of 221.2 and 212.5 mAh g^-1 at 0.2C (40 mA g^-1) with corresponding residual discharge capacities of 177.3 and 156.1 mAh g^-1 after 80 cycles, respectively. Even at high current rates of 2C and 5C, CG-LNCM exhibits high discharge capacities of 165.1 and 149.1 mAh g^-1 after 100 cycles, respectively, while the residual discharge capacities of CC-LNCM are as low as 148.8 and 117.9 mAh g^-1 at 2C and 5C after 100 cycles, respectively. The significantly improved electrochemical performance of CG-LNCM is attributed to its concentration-gradient microstructure and the composition distribution of concentration-gradient LiNi_0.9Co_0.083Mn_0.017O₂. The special concentration-gradient design and the facile synthesis are favorable for massive manufacturing of high-performance Ni-rich ternary cathode materials for lithium-ion batteries.

SUBMITTER: Li H 

PROVIDER: S-EPMC10142341 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature