Taming the parent oxoborane.

ABSTRACT: Despite recent advancements in the chemistry of multiply bound boron compounds, the laboratory isolation of the parent oxoborane moiety, HBO has long remained an unsolved and well-recognized challenge. The reaction of 6-SIDipp·BH₃ [6-SIDipp = 1,3-di(2,6-diisopropylphenyl)tetrahydropyrimidine-2-ylidene] with GaCl₃ afforded an unusual boron-gallium 3c-2e compound (1). The addition of water to 1 resulted in the release of H₂ and the formation of a rare acid stabilized neutral parent oxoborane, LB(H)[double bond, length as m-dash]O (2). Crystallographic and density functional theory (DFT) analyses support the presence of a terminal B[double bond, length as m-dash]O double bond. Subsequent addition of another equivalent of water molecule led to hydrolysis of the

SUBMITTER: Kundu G 

PROVIDER: S-EPMC10246693 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature