Formation of Heterobimetallic Complexes by Addition of d¹⁰-Metal Ions to [(Me₃P)_xM(2-C₆F₄PPh₂)₂] (x = 1, 2; M = Ni and Pt): A Synthetic and Computational Study of Metallophilic Interactions.

ABSTRACT: Treatment of the bis(chelate) complexes trans-[M(κ²-2-C₆F₄PPh₂)₂] (trans-1M; M = Ni, Pt) and cis-[Pt(κ²-2-C₆F₄PPh₂)₂] (cis-1Pt) with equimolar amounts or excess of PMe₃ solution gave complexes of the type [(Me₃P)_xM(2-C₆F₄PPh₂)₂] (x = 2: 2M^a, 2M^b x = 1: 3M^a, 3M^b; M = Ni, Pt). The reactivity of complexes of the type 2M and 3M toward monovalent coinage metal ions (M' = Cu, Ag, Au) was investigated next to the reaction of 1M towa

SUBMITTER: Gericke R 

PROVIDER: S-EPMC10265710 | biostudies-literature | 2023 Jun

REPOSITORIES: biostudies-literature