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Synthesis of Si/C Composites by Silicon Waste Recycling and Carbon Coating for High-Capacity Lithium-Ion Storage.


ABSTRACT: It is of great significance to recycle the silicon (Si) kerf slurry waste from the photovoltaic (PV) industry. Si holds great promise as the anode material for Li-ion batteries (LIBs) due to its high theoretical capacity. However, the large volume expansion of Si during the electrochemical processes always leads to electrode collapse and a rapid decline in electrochemical performance. Herein, an effective carbon coating strategy is utilized to construct a precise Si@CPPy composite using cutting-waste silicon and polypyrrole (PPy). By optimizing the mass ratio of Si and carbon, the Si@CPPy composite can exhibit a high specific capacity and superior rate capability (1436 mAh g-1 at 0.1 A g-1 and 607 mAh g-1 at 1.0 A g-1). More

SUBMITTER: Huang J 

PROVIDER: S-EPMC10386753 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature