Fabrication and properties of Sn(iv) porphyrin-linked porous organic polymer for environmental applications.

ABSTRACT: A robust porous organic polymer cross-linked by Sn(iv) porphyrin (SnPOP) was fabricated by reacting trans-dihydroxo-[5,15,10,20-tetrakis(phenyl)porphyrinato]tin(iv) (SnP) with fluorinated polyimide (FPI) via sol-gel formation, followed by supercritical CO₂ drying. The structural and porous properties of SnPOP were characterized using FT-IR, UV-vis, and fluorescence spectroscopies, along with field-emission scanning electron microscopy and gas sorption experiments. The reaction between the SnP's oxophilic Sn(iv) center and FPI's carboxylic acid moiety resulted in a controllable cross-linked porous texture. This material features the desirable physical properties of porphyrin and exhibits mesoporous structures with a relatively high surface area. SnPOP is thermally s

SUBMITTER: Lee CJ 

PROVIDER: S-EPMC10415751 | biostudies-literature | 2023 Aug

REPOSITORIES: biostudies-literature