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Investigation of the Release Rate of Biocide and Corrosion Resistance of Vinyl-, Acrylic-, and Epoxy-Based Antifouling Paints on Steel in Marine Infrastructures.

ABSTRACT: This study comprehensively assesses the release rate of biocides, corrosion effects related to antifouling, and the physical properties of different paint types. Tests were conducted to measure thickness, viscosity, hardness, bending, adhesion, gloss, impact resistance, abrasion resistance, scratch resistance, polarization, and salt spray. The paints evaluated include resin-based, acrylic-based, epoxy-based, and vinyl-based formulations. The study investigates the influence of biocide content, biocide particle size, and immersion time on release rate using a lab-scale setup. Results showed that acrylic-based paints had a higher biocide release rate due to faster hydrolysis, while smaller biocide particle sizes led to higher release rates in resin-based paints. Optimal total biocide contents were determined to be 30% for acrylic-based, 60% for epoxy-based, and 50% for vinyl-based paints. Antifouling corrosion analysis demonstrated that sample with an optimal release rate effectively prevent algae growth and fouling. Acrylic-based paint with 30 wt.% biocide content exhibited superior adhesion with a dolly separation force of 4.12 MPa. Evaluating the impact of synthesized polyaniline on 30 wt.% epoxy-based paint, a sample coated with 10 wt.% polyaniline represented a low corrosion rate of 0.35 µm/year and a high impedance value of approximately 37,000 Ohm·cm^-2.

SUBMITTER: Jalaie A

PROVIDER: S-EPMC10575080 | biostudies-literature | 2023 Sep

REPOSITORIES: biostudies-literature

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Investigation of the Release Rate of Biocide and Corrosion Resistance of Vinyl-, Acrylic-, and Epoxy-Based Antifouling Paints on Steel in Marine Infrastructures.

Jalaie Adel A Afshaar Abdolah A Mousavi Seyed Borhan SB Heidari Mohammad M

Polymers 20230929 19

This study comprehensively assesses the release rate of biocides, corrosion effects related to antifouling, and the physical properties of different paint types. Tests were conducted to measure thickness, viscosity, hardness, bending, adhesion, gloss, impact resistance, abrasion resistance, scratch resistance, polarization, and salt spray. The paints evaluated include resin-based, acrylic-based, epoxy-based, and vinyl-based formulations. The study investigates the influence of biocide content, b ...[more]

PMID: 37835996

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Project description:Coiled tubing corrosion was investigated for 16 field water samples (S5 to S20) from a Canadian shale gas field. Weight loss corrosion rates of carbon steel beads incubated with these field water samples averaged 0.2 mm/yr, but injection water sample S19 had 1.25±0.07 mm/yr. S19 had a most probable number of zero acid-producing bacteria and incubation of S19 with carbon steel beads or coupons did not lead to big changes in microbial community composition. In contrast other field water samples had most probable numbers of APB of 102/mL to 107/mL and incubation of these field water samples with carbon steel beads or coupons often gave large changes in microbial community composition. HPLC analysis indicated that all field water samples had elevated concentrations of bromide (average 1.6 mM), which may be derived from bronopol, which was used as a biocide. S19 had the highest bromide concentration (4.2 mM) and was the only water sample with a high concentration of active bronopol (13.8 mM, 2760 ppm). Corrosion rates increased linearly with bronopol concentration, as determined by weight loss of carbon steel beads, for experiments with S19, with filtered S19 and with bronopol dissolved in defined medium. This indicated that the high corrosion rate found for S19 was due to its high bronopol concentration. The corrosion rate of coiled tubing coupons also increased linearly with bronopol concentration as determined by electrochemical methods. Profilometry measurements also showed formation of multiple pits on the surface of coiled tubing coupon with an average pit depth of 60 μm after 1 week of incubation with 1 mM bronopol. At the recommended dosage of 100 ppm the corrosiveness of bronopol towards carbon steel beads was modest (0.011 mm/yr). Higher concentrations, resulting if biocide is added repeatedly as commonly done in shale gas operations, are more corrosive and should be avoided. Overdosing may be avoided by assaying the presence of residual biocide by HPLC, rather than by assaying the presence of residual surviving bacteria.

Dataset Information

Investigation of the Release Rate of Biocide and Corrosion Resistance of Vinyl-, Acrylic-, and Epoxy-Based Antifouling Paints on Steel in Marine Infrastructures.

Publications

Investigation of the Release Rate of Biocide and Corrosion Resistance of Vinyl-, Acrylic-, and Epoxy-Based Antifouling Paints on Steel in Marine Infrastructures.

Similar Datasets

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