Surface-catalyzed hydrolysis by pyrogenic carbonaceous matter and model polymers: An experimental and computational study on functional group and pore characteristics.

ABSTRACT: We employed a polymer network to understand what properties of pyrogenic carbonaceous matter (PCM; e.g., activated carbon) confer its reactivity, which we hereinafter referred to as PCM-like polymers (PLP). This approach allows us to delineate the role of functional groups and micropore characteristics using 2,4,6-trinitrotoluene (TNT) as a model contaminant. Six PLP were synthesized via cross-coupling chemistry with specific functionality (-OH, -NH₂, -N(CH₃)₂, or -N(CH3)3+) and pore characteristics (mesopore, micropore). Results suggest that PCM functionality catalyzed the reaction by: (1) serving as a weak base (-OH, -NH₂) to attack TNT, or (2) accumulating OH^- near PCM surfaces (-N(CH3)3+). Additionally, TNT hydrolysis rates,

SUBMITTER: Li Z 

PROVIDER: S-EPMC10578355 | biostudies-literature | 2022 Dec

REPOSITORIES: biostudies-literature