Capturing critical gem-diol intermediates and hydride transfer for anodic hydrogen production from 5-hydroxymethylfurfural.

ABSTRACT: The non-classical anodic H₂ production from 5-hydroxymethylfurfural (HMF) is very appealing for energy-saving H₂ production with value-added chemical conversion due to the low working potential (~0.1 V vs RHE). However, the reaction mechanism is still not clear due to the lack of direct evidence for the critical intermediates. Herein, the detailed mechanisms are explored in-depth using in situ Raman and Infrared spectroscopy, isotope tracking, and density functional theory calculations. The HMF is observed to form two unique inter-convertible gem-diol intermediates in an alkaline medium: 5-(Dihydroxymethyl)furan-2-methanol anion (DHMFM^-) and dianion (DHMFM^2-). The DHMFM^2- is easily oxidized to produce H₂ via H^- tr

SUBMITTER: Fu G 

PROVIDER: S-EPMC10728175 | biostudies-literature | 2023 Dec

REPOSITORIES: biostudies-literature