Bis[2,6-bis-(benzimidazol-2-yl)pyridine-κ³N,N',N'']nickel(II) bis-(tri-fluoro-methane-sulfonate) diethyl ether monosolvate.

ABSTRACT: In the title complex, [Ni(C₁₉H₁₃N₅)₂](CF₃SO₃)₂·(CH₃CH₂)₂O, the central Ni^II atom is sixfold coordinated by three nitro-gen atoms of each 2,6-bis-(2-benzimidazol-yl)pyridine ligand in a distorted octa-hedral geometry with two tri-fluoro-methane-sulfonate ions and a mol-ecule of diethyl ether completing the outer coordination sphere of the complex. Hydrogen bonding contributes to the organization of the asymmetric units in columns along the a axis generating a porous supra-molecular structure. The structure was refined as a two-component twin with a refined BASF value of 0.4104 (13).

SUBMITTER: Ruiz SE 

PROVIDER: S-EPMC10842276 | biostudies-literature | 2024 Jan

REPOSITORIES: biostudies-literature