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Crystal structure and Hirshfeld surface analysis of (Z)-N-{chloro-[(4-ferrocenylphen-yl)imino]-meth-yl}-4-ferrocenylaniline N,N-di-methyl-formamide monosolvate.

ABSTRACT: The title mol-ecule, [Fe2(C5H5)2(C23H17ClN2)]·C3H7NO, is twisted end to end and the central N/C/N unit is disordered. In the crystal, several C-H⋯π(ring) inter-actions lead to the formation of layers, which are connected by further C-H⋯π(ring) inter-actions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H⋯H (60.2%) and H⋯C/C⋯H (27.0%) inter-actions. Hydrogen bonding, C-H⋯π(ring) inter-actions and van der Waals inter-actions dominate the crystal packing.

SUBMITTER: Sghyar R 

PROVIDER: S-EPMC10915674 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature

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Crystal structure and Hirshfeld surface analysis of (<i>Z</i>)-<i>N</i>-{chloro-[(4-ferrocenylphen-yl)imino]-meth-yl}-4-ferrocenylaniline <i>N</i>,<i>N</i>-di-methyl-formamide monosolvate.

Sghyar Riham R   Bentama Abdeslem A   Haoudi Amal A   Mazzah Ahmed A   Mague Joel T JT   Hökelek Tuncer T   El Hadrami El Mestafa EM   Sebbar Nada Kheira NK  

Acta crystallographica. Section E, Crystallographic communications 20240202 Pt 3

The title mol-ecule, [Fe<sub>2</sub>(C<sub>5</sub>H<sub>5</sub>)<sub>2</sub>(C<sub>23</sub>H<sub>17</sub>ClN<sub>2</sub>)]·C<sub>3</sub>H<sub>7</sub>NO, is twisted end to end and the central N/C/N unit is disordered. In the crystal, several C-H⋯π(ring) inter-actions lead to the formation of layers, which are connected by further C-H⋯π(ring) inter-actions. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H⋯H (60  ...[more]

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