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Blighia sapida Waste Biochar in Batch and Fixed-Bed Adsorption of Chloroquine Phosphate: Efficacy Validation Using Artificial Neural Networks.


ABSTRACT: The present study investigated the potency of biochar prepared from Blighia sapida seedpods (BSSPs) in the uptake of chloroquine phosphate (CQP) from single-component batch and multicomponent fixed-bed adsorption systems. BSSPs presented a highly porous structure with a BET surface area of 1122.05 m2/g, to which adsorption efficiency correlated. The Dubinin-Radushkevich isotherm energy was obtained as 129.09 kJ/mol, confirming the chemisorption nature of the BSSP-CQP adsorption system. The efficiency of the artificial neural network (ANN) was evaluated using the lowest mean square error (MSE = 7.27) and highest correlation coefficient (R2 = 0.9910). A good agreement between the experimental results and the ANN-predicted data indicated the efficiency of the model. The percentage removal of 95.78% obtained for the column adsorption studies indicated the effectiveness of BSSPs in a multicomponent system. The mechanism of the interaction proceeded via hydrogen bonding and electrostatic attraction. This was confirmed by the high desorption efficiency (69.11%) with a HCl eluent. The degree of reversibility was found to be 2.95, indicating the reusability potential of BSSPs. BSSPs are therefore considered multilayered adsorbents with potential applications in pharmaceutical wastewater treatment.

SUBMITTER: Inyinbor AA 

PROVIDER: S-EPMC10955583 | biostudies-literature | 2024 Mar

REPOSITORIES: biostudies-literature

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<i>Blighia sapida</i> Waste Biochar in Batch and Fixed-Bed Adsorption of Chloroquine Phosphate: Efficacy Validation Using Artificial Neural Networks.

Inyinbor Adejumoke Abosede AA   Bankole Deborah Temitope DT   Oluyori Abimbola Peter AP  

ACS omega 20240306 11


The present study investigated the potency of biochar prepared from <i>Blighia sapida</i> seedpods (BSSPs) in the uptake of chloroquine phosphate (CQP) from single-component batch and multicomponent fixed-bed adsorption systems. BSSPs presented a highly porous structure with a BET surface area of 1122.05 m<sup>2</sup>/g, to which adsorption efficiency correlated. The Dubinin-Radushkevich isotherm energy was obtained as 129.09 kJ/mol, confirming the chemisorption nature of the BSSP-CQP adsorption  ...[more]

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