Ontology highlight
ABSTRACT:
SUBMITTER: Cook EN
PROVIDER: S-EPMC10979433 | biostudies-literature | 2024 Mar
REPOSITORIES: biostudies-literature

Cook Emma N EN Davis Anna E AE Hilinski Michael K MK Machan Charles W CW
Journal of the American Chemical Society 20240315 12
The oxygen reduction reaction (ORR) is important for alternative energy and industrial oxidation processes. Herein, an iminium-based organoelectrocatalyst (<b>im</b><sup><b>+</b></sup>) for the ORR with trifluoroacetic acid as a proton source in acetonitrile solution under both electrochemical and spectrochemical conditions using decamethylferrocene as a chemical reductant is reported. Under spectrochemical conditions, H<sub>2</sub>O<sub>2</sub> is the primary reaction product, while under elect ...[more]