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ABSTRACT:
SUBMITTER: Kimoto M
PROVIDER: S-EPMC11229008 | biostudies-literature | 2024 Jul
REPOSITORIES: biostudies-literature
Kimoto Momoka M Sugiyama Shoichi S Kumano Keigo K Inagaki Satoshi S Ito Suguru S
Journal of the American Chemical Society 20240625 26
Despite recent advances in porous organic molecular crystals, the engineering of dual-pore systems within the intermolecular voids remains a significant challenge. In this study, we have achieved the crystallization-induced social self-sorting of "quasi-racemic" dialdehydes into a macrocyclic imine. X-ray crystallographic analysis unambiguously characterizes the resulting structure as incorporating two quasi-racemate pairs with four diamine molecules. Notably, different alkyl substituents on the ...[more]