URJC-1: Stable and Efficient Catalyst for O-Arylation Cross-Coupling.

ABSTRACT: The design of metal-organic frameworks (MOFs) allows the definition of properties for their final application in small-scale heterogeneous catalysis. Incorporating various catalytic centers within a single structure can produce a synergistic effect, which is particularly intriguing for cross-coupling reactions. The URJC-1 material exhibits catalytic duality: the metal centers act as Lewis acid centers, while the nitrogen atoms of the organic ligand must behave as basic centers. The impact of reaction temperature, catalyst concentration, and basic agent concentration was evaluated. Several copper-based catalysts, including homogeneous and heterogeneous MOF catalysts with and without the presence of nitrogen atoms in the organic ligand, were assessed for their catalytic effect under optimal

SUBMITTER: Garcia-Rojas E 

PROVIDER: S-EPMC11243573 | biostudies-literature | 2024 Jun

REPOSITORIES: biostudies-literature