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Zn(OTf)2-catalyzed intra- and intermolecular selenofunctionalization of alkenes under mild conditions.


ABSTRACT: Zn(OTf)2-catalyzed intra- and intermolecular selenofunctionalization of alkenes was achieved with electrophilic N-phenylselenophthalimide. This method provides straightforward and efficient access to various seleno-substituted heterocycles and vicinal Se heteroatom-disubstituted molecules under mild conditions. This reaction is compatible with various substrates/functional groups, and preliminary studies on the reaction mechanistic were also conducted.

SUBMITTER: Qi C 

PROVIDER: S-EPMC11262084 | biostudies-literature | 2024 Jul

REPOSITORIES: biostudies-literature

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Zn(OTf)<sub>2</sub>-catalyzed intra- and intermolecular selenofunctionalization of alkenes under mild conditions.

Qi Cong C   Lu Zhaogong Z   Gu Yuyang Y   Bao Xiaofeng X   Xiong Biao B   Liu Gong-Qing GQ  

RSC advances 20240722 32


Zn(OTf)<sub>2</sub>-catalyzed intra- and intermolecular selenofunctionalization of alkenes was achieved with electrophilic <i>N</i>-phenylselenophthalimide. This method provides straightforward and efficient access to various seleno-substituted heterocycles and vicinal Se heteroatom-disubstituted molecules under mild conditions. This reaction is compatible with various substrates/functional groups, and preliminary studies on the reaction mechanistic were also conducted. ...[more]

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