Novel ball-milled biochar-vermiculite nanocomposites effectively adsorb aqueous As(Ⅴ).

ABSTRACT: Ball milling was used to fabricate a nanocomposite of 20% hickory biochar (600 °C) and 80% expanded vermiculite (20%-BC/VE). This novel composite adsorbent had much higher removal of As(V) from aqueous solutions than ball-milled biochar and expanded vermiculite. Characterization of these adsorbents showed that the enhanced As(V) adsorption was ascribed to much larger surface area and pore volume (2-6 times), notable changes in crystallinity, activation of cations, and increased functional groups in the nanocomposite compared with the ball-milled products of their pristine counterparts. The As(V) adsorption process by the 20%-BC/VE fitted well with the pseudo-second-order kinetic model (R²= 0.990) and Langmuir isotherm model (R²= 0.989) with a maximum adsorption capaci

SUBMITTER: Li F 

PROVIDER: S-EPMC11346315 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature