Understanding the Dynamics of Sulfur Droplets Formation in Lean-Electrolyte and Low-Temperature Lithium-Sulfur Batteries.

ABSTRACT: Lithium-sulfur batteries (LSBs) afford great promises as the next-generation rechargeable batteries due to the high energy density and low cost of sulfur cathodes. Lean-electrolyte condition constitutes the prerequisite for high-energy LSBs, but the insulating sulfur particles hinder capacity utilization, especially at low temperatures. Here, the electrochemical generation of liquid sulfur droplets in the LSB system are studied and elucidate the polysulfide oxidation reaction (SOR) kinetics under different electrolyte/sulfur (E/S) ratios and low-temperature conditions. The real-time observations under in situ optical and Raman microscopies indicate that the formation of liquid sulfur during SOR is independent of the E/S ratio and can be preserved over a wide range of operating temperatures

SUBMITTER: Qi Q 

PROVIDER: S-EPMC11775558 | biostudies-literature | 2025 Jan

REPOSITORIES: biostudies-literature