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Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture.


ABSTRACT: A new organically templated homochiral material (EMIm)[Co 2( d-cam) 2(ac)] ( 1; d-H 2cam = d-camphoric acid; ac = acetate; EMIm = 1-ethyl-3-methylimidazolium) has been ionothermally synthesized, and it features an unusual acetate-pillared cobalt-camphorate architecture encapsulating the cationic component of the ionic liquid.

SUBMITTER: Chen S 

PROVIDER: S-EPMC2766170 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Ionothermal synthesis of homochiral framework with acetate-pillared cobalt-camphorate architecture.

Chen Shumei S   Zhang Jian J   Bu Xianhui X  

Inorganic chemistry 20080607 13


A new organically templated homochiral material (EMIm)[Co 2( d-cam) 2(ac)] ( 1; d-H 2cam = d-camphoric acid; ac = acetate; EMIm = 1-ethyl-3-methylimidazolium) has been ionothermally synthesized, and it features an unusual acetate-pillared cobalt-camphorate architecture encapsulating the cationic component of the ionic liquid. ...[more]

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