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(1R,2R)-4-Benzoyl-2-benzo-yloxy-1-phenyl-butyl imidazole-1-carboxyl-ate.

ABSTRACT: The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenyl-propane-1,3-dione using standard Sharpless asymmetric dihydroxy-lation conditions, followed by treatment with 1,1'-carbonyl diimidazole. In the crystal structure, the phenyl rings form inter-molecular face-to-face ?-? contacts, with an inter-planar angle of 15.5?(2)° and a centroid-centroid distance of 4.73?(1)?Å. One phenyl ring also forms a C-H?? contact to an adjacent imidazole ring, with an H?centroid distance of 3.18?Å.

SUBMITTER: Fox DJ 

PROVIDER: S-EPMC2960783 | biostudies-literature | 2008 Feb

REPOSITORIES: biostudies-literature

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(1R,2R)-4-Benzoyl-2-benzo-yloxy-1-phenyl-butyl imidazole-1-carboxyl-ate.

Fox David J DJ   Parris Sean S   Pedersen Daniel Sejer DS   Warren Stuart S  

Acta crystallographica. Section E, Structure reports online 20080222 Pt 3

The title compound, C(28)H(24)N(2)O(5), was prepared from (E)-2-cinnamyl-1,3-diphenyl-propane-1,3-dione using standard Sharpless asymmetric dihydroxy-lation conditions, followed by treatment with 1,1'-carbonyl diimidazole. In the crystal structure, the phenyl rings form inter-molecular face-to-face π-π contacts, with an inter-planar angle of 15.5 (2)° and a centroid-centroid distance of 4.73 (1) Å. One phenyl ring also forms a C-H⋯π contact to an adjacent imidazole ring, with an H⋯centroid dista  ...[more]

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