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Bis(O,O'-diphenethyl dithio-phosphato-κS,S')bis-(4-methyl-pyridine-κN)nickel(II).

ABSTRACT: The title complex, [Ni(C(16)H(18)O(2)PS(2))(2)(C(6)H(7)N)(2)], exhibits a roughly octa-hedral coordination geometry. The Ni(II) atom lies on an inversion centre and is coordinated by four S atoms of O,O'-diphenethyl dithio-phosphate mol-ecules and two N atoms of 4-methyl-pyridine mol-ecules. Important geometric data include Ni-N = 2.100 (3) Å, and Ni-S = 2.5101 (10) and 2.4772 (11) Å.

SUBMITTER: Feng JS

PROVIDER: S-EPMC2961944 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Bis(O,O'-diphenethyl dithio-phosphato-κS,S')bis-(4-methyl-pyridine-κN)nickel(II).

Feng Jian-Shen JS Cheng Yu Y Zou Li-Ke LK Xie Bin B Zhang Xiu-Lan XL

Acta crystallographica. Section E, Structure reports online 20080712 Pt 8

The title complex, [Ni(C(16)H(18)O(2)PS(2))(2)(C(6)H(7)N)(2)], exhibits a roughly octa-hedral coordination geometry. The Ni(II) atom lies on an inversion centre and is coordinated by four S atoms of O,O'-diphenethyl dithio-phosphate mol-ecules and two N atoms of 4-methyl-pyridine mol-ecules. Important geometric data include Ni-N = 2.100 (3) Å, and Ni-S = 2.5101 (10) and 2.4772 (11) Å. ...[more]

PMID: 21203014

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