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Tricyclo-hexyl(piperidine-1-dithio-carboxyl-ato-κS)tin(IV).

ABSTRACT: In the title compound, [Sn(C(6)H(11))(3)(C(6)H(10)NS(2))], the Sn(IV) atom is tetra-coordinated by three C atoms from cyclo-hexyl groups and one S atom from a piperidine-dithio-carboxyl-ate anion. The coordination geometry is distorted tetra-hedral, with Sn-C bond lengths in the range 2.133 (6)-2.188 (6) Å and with an Sn-S bond length of 2.4516 (19) Å. The nonbonded S atom of the piperidine-dithio-carboxyl-ate anion makes an Sn⋯S contact of 3.174 (3) Å.

SUBMITTER: Hao L

PROVIDER: S-EPMC2961956 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Tricyclo-hexyl(piperidine-1-dithio-carboxyl-ato-κS)tin(IV).

Hao Lujiang L Mu Chunhua C Kong Binbin B

Acta crystallographica. Section E, Structure reports online 20080716 Pt 8

In the title compound, [Sn(C(6)H(11))(3)(C(6)H(10)NS(2))], the Sn(IV) atom is tetra-coordinated by three C atoms from cyclo-hexyl groups and one S atom from a piperidine-dithio-carboxyl-ate anion. The coordination geometry is distorted tetra-hedral, with Sn-C bond lengths in the range 2.133 (6)-2.188 (6) Å and with an Sn-S bond length of 2.4516 (19) Å. The nonbonded S atom of the piperidine-dithio-carboxyl-ate anion makes an Sn⋯S contact of 3.174 (3) Å. ...[more]

PMID: 21203026

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