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(Z)-Methyl 4-({3-[(2,5-dioxoimidazolidin-4-yl-idene)meth-yl]-1H-indol-1-yl}meth-yl)benzoate.

ABSTRACT: In the title compound, C(21)H(17)N(3)O(4), pairs of mol-ecules form a planar[maximum deviation 0.0566 (9) Å] centrosymmetric imidazole dimer via two N-H⋯O hydrogen bonds. These dimeric units are linked by further N-H⋯O hydrogen bonds between the ester carbonyl group and the imidazolidine ring, formiing chains parallel to the c-axis direction. In addition, there are π-π stacking inter-actions between the planar imidazole pairs, with an inter-planar spacing of 3.301 (2) Å. There is a double bond with Z geometry connecting the imidazolidine and indole units.

SUBMITTER: Penthala NR 

PROVIDER: S-EPMC2967975 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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(Z)-Methyl 4-({3-[(2,5-dioxoimidazolidin-4-yl-idene)meth-yl]-1H-indol-1-yl}meth-yl)benzoate.

Penthala Narsimha Reddy NR   Reddy Thirupathi Reddy Yerram TR   Parkin Sean S   Crooks Peter A PA  

Acta crystallographica. Section E, Structure reports online 20081210 Pt 1

In the title compound, C(21)H(17)N(3)O(4), pairs of mol-ecules form a planar[maximum deviation 0.0566 (9) Å] centrosymmetric imidazole dimer via two N-H⋯O hydrogen bonds. These dimeric units are linked by further N-H⋯O hydrogen bonds between the ester carbonyl group and the imidazolidine ring, formiing chains parallel to the c-axis direction. In addition, there are π-π stacking inter-actions between the planar imidazole pairs, with an inter-planar spacing of 3.301 (2) Å. There is a double bond w  ...[more]

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