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Dichloridobis(1,10-phenanthroline-5,6-dione-κN,N')mercury(II).

ABSTRACT: In the title compound, [HgCl(2)(C(12)H(6)N(2)O(2))(2)], the Hg(II) atom is located on a twofold rotation axis and exists within a distorted octa-hedral geometry defined by a cis-Cl(2)N(4) donor set. Mol-ecules are connected into layers in the ac plane via extensive C-H⋯Cl contacts as each Cl atom forms two such inter-actions. Contacts between the layers are of the type C=O⋯π [O⋯centroid distance = 3.110 (8) Å].

SUBMITTER: Figueiras CA

PROVIDER: S-EPMC2971919 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Dichloridobis(1,10-phenanthroline-5,6-dione-κN,N')mercury(II).

Figueiras Carlos A L CA Bomfim João A S JA Howie R Alan RA Tiekink Edward R T ER Wardell James L JL

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

In the title compound, [HgCl(2)(C(12)H(6)N(2)O(2))(2)], the Hg(II) atom is located on a twofold rotation axis and exists within a distorted octa-hedral geometry defined by a cis-Cl(2)N(4) donor set. Mol-ecules are connected into layers in the ac plane via extensive C-H⋯Cl contacts as each Cl atom forms two such inter-actions. Contacts between the layers are of the type C=O⋯π [O⋯centroid distance = 3.110 (8) Å]. ...[more]

PMID: 21578658

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