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Poly[1,4-bis-(ammonio-meth-yl)cyclo-hexane [di-μ-chlorido-dichloridoplumbate(II)]].

ABSTRACT: The title compound, {(C(8)H(20)N(2))[PbCl(4)]}(n), crystallizes as an layered inorganic-organic hybrid perovskite-type structure. Corner-sharing PbCl(6) octa-hedra extend parallel to the ac plane. Adjacent layers are staggered relative to one another, with diammonium cations separating these layers. The cations exhibit symmetry and inter-act with the inorganic sheets via N-H⋯Cl hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.

SUBMITTER: Rayner MK 

PROVIDER: S-EPMC2979563 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Poly[1,4-bis-(ammonio-meth-yl)cyclo-hexane [di-μ-chlorido-dichloridoplumbate(II)]].

Rayner Matthew Kyle MK   Billing David Gordon DG  

Acta crystallographica. Section E, Structure reports online 20100515 Pt 6

The title compound, {(C(8)H(20)N(2))[PbCl(4)]}(n), crystallizes as an layered inorganic-organic hybrid perovskite-type structure. Corner-sharing PbCl(6) octa-hedra extend parallel to the ac plane. Adjacent layers are staggered relative to one another, with diammonium cations separating these layers. The cations exhibit symmetry and inter-act with the inorganic sheets via N-H⋯Cl hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif. ...[more]

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