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Di-μ-azido-bis-({N'-[1-(2-pyrid-yl-κN)ethyl-idene]acetohydrazidato-κN',O}dicopper(II)).

ABSTRACT: The dimeric title compound, [Cu(2)(C(9)H(10)N(3)O)(2)(N(3))(2)], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C-H⋯N hydrogen bonds link the dimers into chains along the c axis.

SUBMITTER: Datta A

PROVIDER: S-EPMC2983124 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Di-μ-azido-bis-({N'-[1-(2-pyrid-yl-κN)ethyl-idene]acetohydrazidato-κN',O}dicopper(II)).

Datta Amitabha A Das Kuheli K Jhou Yan-Ming YM Huang Jui-Hsien JH Lee Hon Man HM

Acta crystallographica. Section E, Structure reports online 20100918 Pt 10

The dimeric title compound, [Cu(2)(C(9)H(10)N(3)O)(2)(N(3))(2)], is located on a crystallographic inversion center. The Cu atom is coordinated by a tridentate anionic hydrazone ligand and two bridging azide ligands in a distorted square-pyramidal coordination geometry. The non-bonding Cu⋯Cu distance is 3.238 (1) Å. Non-classical inter-molecular C-H⋯N hydrogen bonds link the dimers into chains along the c axis. ...[more]

PMID: 21587416

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