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Poly[[diaqua-(1,10-phenanthroline-κN,N')(μ(3)-4-sulfonato-benzene-1,2-di-car-boxyl-ato-κO:O,O:O)erbium(III)] dihydrate].

ABSTRACT: The 4-sulfophthalate trianion in the polymeric complex, {[Er(C(8)H(3)O(7)S)(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), bridges three water/phenanthroline-coordinated Er(III) ions to form a three-dimensional network architecture. The metal atom is further chelated by a carboxyl-ate group and is covalently bonded to a monodentate carboxyl-ate group as well as to a monodentate sulfonate group in a distorted square anti-prismatic geometry. The coordinating water molecules and the lattice water molecules, one of which is disordered over two positions [major component 65 (3)%], are hydrogen bonded to the network.

SUBMITTER: Zhang KL

PROVIDER: S-EPMC3274939 | biostudies-literature | 2012 Feb

REPOSITORIES: biostudies-literature

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Poly[[diaqua-(1,10-phenanthroline-κN,N')(μ(3)-4-sulfonato-benzene-1,2-di-car-boxyl-ato-κO:O,O:O)erbium(III)] dihydrate].

Zhang Kou-Lin KL Lin Jian-Guo JG Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20120131 Pt 2

The 4-sulfophthalate trianion in the polymeric complex, {[Er(C(8)H(3)O(7)S)(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), bridges three water/phenanthroline-coordinated Er(III) ions to form a three-dimensional network architecture. The metal atom is further chelated by a carboxyl-ate group and is covalently bonded to a monodentate carboxyl-ate group as well as to a monodentate sulfonate group in a distorted square anti-prismatic geometry. The coordinating water molecules and the lattice water molecules, ...[more]

PMID: 22346886

Similar Datasets

Poly[[diaqua-(1,10-phenanthroline-?N,N')(?(3)-4-sulfonato-benzene-1,2-dicarboxyl-ato-?O:O,O:O)dysprosium(III)] dihydrate].

Project description:The 4-sulfophthalate trianion in the polymeric title complex, {[Dy(C(8)H(3)O(7)S)(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O}(n), bridges three water/phenanthroline-coordinated Dy(III) atoms to form a three-dimensional network architecture. The metal atom is further chelated by a carboxyl-ate group and is covalently bonded to a monodentate carboxyl-ate group and to a monodentate sulfonate group in a distorted square-anti-prismatic geometry. The coordinating and the solvent water mol-ecules are hydrogen bonded to the network. In the crystal, one solvent water mol-ecule is disordered over two positions [major component = 59?(3)%].

| S-EPMC3297213 | biostudies-other

Bis(1H-benzotriazole-7-sulfonato-κO)bis-(1,10-phenanthroline-κN,N')cadmium dihydrate.

Project description:In the title complex, [Cd(C(6)H(4)N(3)O(3)S)(2)(C(12)H(8)N(2))(2)]·2H(2)O, the Cd(2+) cation is located on an inversion center and is coordinated by four N atoms from two symmetry-related 1,10-phenanthroline ligands and two sulfonate O atoms from two benzotriazole-7-sulfonate anions, displaying a distorted CdN(4)O(2) octa-hedral geometry. In the crystal, O-H⋯N, O-H⋯O, N-H⋯O, C-H⋯N and C-H⋯O hydrogen bonds occur. The lattice water mol-ecules and sulfonate O atoms as donor or acceptor atoms play important roles in the formation of these inter-actions.

| S-EPMC3238623 | biostudies-literature

Bis(1,10-phenanthroline-κN,N')[2-(4-sulfonato-anilino)acetato-κO]copper(II) dihydrate.

Project description:In the title compound, [Cu(C(8)H(7)NO(5)S)(C(12)H(8)N(2))(2)]·2H(2)O, the Cu(II) ion is coordinated by four N atoms from two 1,10-phenanthroline (phen) ligands and one O atom from a 2-(4-sulfonato-anilino)acetate (spia) ligand in a distorted square-pyramidal geometry. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds, as well as π-π inter-actions between phen ligands and between phen and spia ligands [centroid-centroid distances = 3.663 (3), 3.768 (3) and 3.565 (3) Å], result in a three-dimensional supra-molecular structure.

| S-EPMC3100003 | biostudies-literature

Bis(4-amino-benzene-sulfonato-κN)diaqua-bis(dimethyl-formamide-κO)nickel(II) dihydrate.

Project description:In the title compound, [Ni(C(6)H(6)NO(3)S)(2)(C(3)H(7)NO)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion (site symmetry ) is coordinated by two -NH(2) groups from two 4-amino-benzene-sulfonate anions, two O atoms from two dimethyl-formamide mol-ecules and two water mol-ecules, forming a slightly distorted trans-NiN(2)O(4) octa-hedral geometry. In the crystal structure, inter-molecular O-H⋯O, O-H⋯(O,O) and N-H⋯O hydrogen bonds link the components into a three-dimensional network. The O atoms of the sulfonate group are disordered over two sets of sites in a 0.833 (4):0.167 (4) ratio and the O atom of the uncoordinated water mol-ecule is disordered over two sites in a 0.637 (18):0.363 (18) ratio.

| S-EPMC2969510 | biostudies-literature

(Acetato-κO)diaqua-[2-(1H-benzotriazol-1-yl)acetato-κO](1,10-phenanthroline-κN,N')manganese(II) dihydrate.

Project description:In the hydrated title complex, [Mn(C(8)H(6)N(3)O(2))(CH(3)CO(2))(C(12)H(8)N(2))(H(2)O)(2)]·2H(2)O, the Mn(II) atom is coordinated by two N atoms from a 1,10-phenanthroline ligand, two water O atoms, a monodentate acetate anion and an O-monodentate 2-(1H-benzotriazol-1-yl)acetate ligand, resulting in a distorted cis-MnN(2)O(4) octa-hedral coordination geometry. The water O atoms are in a trans arrangement and one of them forms an intra-molecular O-H⋯O hydrogen bond to the uncoordinated O atom of the acetate ion. In the crystal, the complex mol-ecules and water mol-ecules are connected by O-H⋯O and O-H⋯N hydrogen bonds to generate a three-dimensional network.

| S-EPMC3297274 | biostudies-literature

Diaqua-(2,9-dimethyl-1,10-phenanthroline-κN,N')(4-hydroxy-benzoato-κO,O')cobalt(II) nitrate dihydrate.

Project description:In the title compound, [Co(C(7)H(5)O(3))(C(14)H(12)N(2))(H(2)O)(2)]NO(3)·2H(2)O, the Co(II) ion is six-coordinated by two N atoms of a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand, two carboxyl-ate O atoms of one 4-hydroxy-benzoate anion and two O atoms of two water mol-ecules, in a distorted octa-hedral environment; the two water mol-ecules occupy the apical positions. In the crystal structure, the ionic units and water mol-ecules are linked through O-H⋯O hydrogen bonds, leading to the formation of a three-dimensional network. In addition, π-π inter-actions between a pyridine ring of the dmphen ligand and the benzene ring of the hydroxy-benzoate anion [centroid-centroid separation = 3.6861 (3) Å] are observed.

| S-EPMC2959819 | biostudies-literature

Triaqua-(1,10-phenanthroline-2,9-dicarboxyl-ato)cobalt(II) dihydrate.

Project description:The title compound, [Co(C(14)H(6)N(2)O(4))(H(2)O)(3)]·2H(2)O, has two-fold crystallographic symmetry. The Co(II) atom is in a distorted penta-gonal-bipyramidal coordination environment with two N atoms and two O atoms from a tetradentate 1,10-phenanthroline-2,9-dicarboxyl-ate ligand and one O atom from a water mol-ecule forming the penta-gonal plane, and two O atoms from two water mol-ecules occupying axial positions. In the crystal, adjacent mol-ecules are linked by O-H⋯O hydrogen bonds, forming a three-dimensional network.

| S-EPMC2983888 | biostudies-literature

(6-Oxido-2-oxo-1,2-dihydropyrimidine-5-carboxylato-κO,O)(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxyl-ato-κO,O)bis(1,10-phenanthroline-κN,N')erbium(III) dihydrate.

Project description:The erbium(III) atom in the title compound, [Er(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(C(12)H(8)N(2))(2)]·2H(2)O, is located on a twofold rotation axis and chelated by two 1,10-phenanthroline heterocycles as well as by a 2,4-dihydroxy-pyrimidine-5-car-box-yl-ate monoanion and a 2,4-dihydroxy-pyrimidine-5-car-box-yl-ate dianion in a square-anti-prismatic coordination geometry.

| S-EPMC2960368 | biostudies-literature

Di-μ-sulfato-κO:O'-bis-[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline-κN,N)cobalt(II)] dihydrate.

Project description:In the centrosymmetric dinuclear title compound, [Co(2)(SO(4))(2)(C(13)H(8)N(4))(2)(H(2)O)(4)]·2H(2)O, the Co(II) atom is coord-in-ated by two N atoms from two 1H-imidazo[4,5-f][1,10]phenanthroline ligands, two O atoms from two sulfate anions and two O atoms from water mol-ecules in a distorted octa-hedral geometry. The Co⋯Co separation is 5.1167 (7) Å. The coordinated and uncoordinated water mol-ecules engage in N-H⋯O and O-H⋯O hydrogen-bonding inter-actions.

| S-EPMC2977338 | biostudies-literature

catena-Poly[[[diaqua-(1,3-benzimidazole-κN)manganese(II)]-μ-benzene-1,3-di-carboxyl-ato-κO,O:O] dihydrate].

Project description:In the polymeric title complex, {[Mn(C(8)H(4)O(4))(C(7)H(6)N(2))(H(2)O)(2)]·2H(2)O}(n), the Mn(II) cation is coordinated by two benzene-dicarboxyl-ate anions, one benzimidazole ligand and two water mol-ecules in a distorted MnNO(5) octa-hedral geometry. In the crystal, each benzene-dicarboxyl-ate anion bridges adjacent Mn(II) cations through the terminal carboxyl-ate groups, forming a polymeric complex chain along the a axis. One Mn-O(carboxyl-ate) bond is much longer than the others. In the crystal, π-π stacking is observed between nearly parallel [dihedral angle = 4.32 (6)°] benzimidazole aromatic ring systems of adjacent mol-ecules, the centroid-centroid distance between the imidazole and benzene rings being 3.5421 (11) Å. Extensive inter-molecular O-H⋯O and N-H⋯O hydrogen bonding is present in the crystal structure. The two lattice water mol-ecules are located on twofold rotation axes.

| S-EPMC3099958 | biostudies-literature

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