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Tetra-kis(1-phenyl-1H-imidazole-κN(3))bis-(thio-cyanato-κN)nickel(II).

ABSTRACT: The title compound, [Ni(NCS)(2)(C(9)H(8)N(2))(4)], crystallizes with two independent half-mol-ecules in the asymmetric unit and the Ni(II) ions situated on centres of symmetry. In both independent mol-ecules, the Ni(II) ion displays a compressed octa-hedral environment formed by four N atoms from the 1-phenyl-1H-imidazole ligands, which define the equatorial plane, with a mean Ni-N distance of 2.119 (11) Å, and two axial N atoms from two NCS(-) anions, with a mean Ni-N distance of 2.079 (7) Å. The crystal packing exhibits weak inter-molecular S⋯S contacts of 3.411 (2) Å.

SUBMITTER: Zheng SM 

PROVIDER: S-EPMC3344356 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

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Tetra-kis(1-phenyl-1H-imidazole-κN(3))bis-(thio-cyanato-κN)nickel(II).

Zheng Shao-Mei SM   Liu Bao-Cheng BC  

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

The title compound, [Ni(NCS)(2)(C(9)H(8)N(2))(4)], crystallizes with two independent half-mol-ecules in the asymmetric unit and the Ni(II) ions situated on centres of symmetry. In both independent mol-ecules, the Ni(II) ion displays a compressed octa-hedral environment formed by four N atoms from the 1-phenyl-1H-imidazole ligands, which define the equatorial plane, with a mean Ni-N distance of 2.119 (11) Å, and two axial N atoms from two NCS(-) anions, with a mean Ni-N distance of 2.079 (7) Å. T  ...[more]

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