Unknown

Dataset Information

0

Catena-Poly[[[aqua-(pyrazine-2-carboxamide-κ(2)N(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)N(1),O:N(4)] dinitrate].

ABSTRACT: In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol-ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa-hedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (-) anions link to the chain via O-H⋯O and N-H⋯O hydrogen bonding. Weak inter-molecular C-H⋯O inter-actions also occur.

SUBMITTER: Shirvan SA 

PROVIDER: S-EPMC3344359 | biostudies-literature | 2012 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[aqua-(pyrazine-2-carboxamide-κ(2)N(1),O)zinc]-μ-pyrazine-2-carboxamide-κ(3)N(1),O:N(4)] dinitrate].

Shirvan Sadif A SA   Haydari Dezfuli Sara S  

Acta crystallographica. Section E, Structure reports online 20120418 Pt 5

In the crystal of the title compound, {[Zn(C(5)H(5)N(3)O)(2)(H(2)O)](NO(3))(2)}(n), the Zn(II) cation is N,O-chelated by two pyrazine-2-carboxamide (PCA) ligands and is further coordinated by one water mol-ecule and by one pyrazine-N atom from an adjacent PCA ligand in a distorted ZnN(3)O(3) octa-hedral geometry. One of the two independent PCA ligands bridges two Zn(II) cations, forming a zigzag polymeric chain running along the c axis. In the crystal, the NO(3) (-) anions link to the chain via  ...[more]

Similar Datasets

Unknown catena-Poly[[tetra-aqua-copper(II)]-μ-pyrazine-2-carboxamide-κ(3)N(4):N(1),O-[bis-(sulfato-κO)copper(II)]-μ-pyrazine-2-carboxamide-κ(3)N(1),O:N(4)].
| S-EPMC3414139 | biostudies-literature
Unknown catena-Poly[aqua-bis-(μ-3-chloro-benzo-ato-κ(2) O:O')zinc].
| S-EPMC3772418 | biostudies-literature
Unknown Crystal structure of catena-poly[[aqua-bis-(4-formyl-benzoato)-κ(2) O (1),O (1');κO (1)-zinc]-μ-pyrazine-κ(2) N:N'].
| S-EPMC4438816 | biostudies-literature
Unknown Crystal structure of catena-poly[[[trans-bis(aceto-nitrile-κN)diaquacobalt(II)]-μ-pyrazine-κ(2) N:N'] dinitrate].
| S-EPMC4770956 | biostudies-literature
Unknown catena-Poly[[aqua-bis-(4-formyl-benzoato-κ(2) O (1),O (1'))cadmium]-μ-pyrazine-κ(2) N:N'].
| S-EPMC3998250 | biostudies-literature
Unknown catena-Poly[[di-aqua-bis-(4-formyl-benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N'].
| S-EPMC3914040 | biostudies-literature
Unknown catena-Poly[[di-aqua-bis-(4-formyl-benzo-ato-κO (1))nickel(II)]-μ-pyrazine-κ(2) N:N'].
| S-EPMC3998267 | biostudies-literature
Unknown catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4,4'-bipyridine-κ(2)N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate].
| S-EPMC3435629 | biostudies-literature
Unknown Crystal structure of catena-poly[[di-aqua-bis-(4-formyl-benzoato-κO (1))cobalt(II)]-μ-pyrazine-κ(2) N:N'].
| S-EPMC4438811 | biostudies-literature
Unknown Crystal structure of catena-poly[[[tetra-aqua-zinc(II)]-μ-1,4-bis-[4-(1H-imidazol-1-yl)benzo-yl]piperazine] dinitrate monohydrate].
| S-EPMC4420132 | biostudies-literature