Ligand effects on Negishi couplings of alkenyl halides.

ABSTRACT: Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been developed that solves the stereochemical issue and significantly improves yields of Negishi couplings in general.

SUBMITTER: Krasovskiy A 

PROVIDER: S-EPMC3365518 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature