Di-aqua-bis-[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]zinc.

ABSTRACT: In the title compound, [Zn(C11H7N6)2(H2O)2], the Zn(II) cation, located on an inversion center, is N,N'-chelated by two 5-(pyrazin-2-yl)-3-(pyridin-3-yl)-1,2,4-triazolide anions and is further coordinated by two water mol-ecules in a distorted N4O2 octa-hedral geometry. In the anionic ligand, the pyrazine and pyridine rings are twisted with respect to the central triazole ring by 5.77 (10) and 11.54 (10)°, respectively. In the crystal, classical O-H⋯N and weak C-H⋯O hydrogen bonds and π-π stacking inter-actions between aromatic rings [the centroid-centroid distances between triazole and pyrazine rings, and between triazole and pyridine rings are 3.623 (2) and 3.852 (2) Å, respectively] connect the mol-ecules into a three-dimensional supra-molecular architecture.

SUBMITTER: Wang YN 

PROVIDER: S-EPMC3998535 | biostudies-literature | 2014 Apr

REPOSITORIES: biostudies-literature