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Crystal structure of (benzene-carbo-thio-amide-κS)chloridobis-(tri-phenyl-phosphane-κP)silver(I).

ABSTRACT: In the mononuclear mixed-ligand title complex, [AgCl(C7H7NS)(C18H15P)2], the Ag(I) ion is four coordinated by one S atom of a benzene-carbo-thio-amide ligand, two P atoms of two tri-phenyl-phosphane ligands and one chloride ion, displaying a distorted tetra-hedral coordination geometry. In the crystal, pairs of N-H⋯Cl hydrogen bonds form inversion dimers. An intra-molecular N-H⋯Cl hydrogen bond is also observed.

SUBMITTER: Ruangwut W

PROVIDER: S-EPMC4186092 | biostudies-literature | 2014 Sep

REPOSITORIES: biostudies-literature

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Crystal structure of (benzene-carbo-thio-amide-κS)chloridobis-(tri-phenyl-phosphane-κP)silver(I).

Ruangwut Wattana W Pakawatchai Chaveng C

Acta crystallographica. Section E, Structure reports online 20140801 Pt 9

In the mononuclear mixed-ligand title complex, [AgCl(C7H7NS)(C18H15P)2], the Ag(I) ion is four coordinated by one S atom of a benzene-carbo-thio-amide ligand, two P atoms of two tri-phenyl-phosphane ligands and one chloride ion, displaying a distorted tetra-hedral coordination geometry. In the crystal, pairs of N-H⋯Cl hydrogen bonds form inversion dimers. An intra-molecular N-H⋯Cl hydrogen bond is also observed. ...[more]

PMID: 25309175

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