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Atropurpuran - Missing Biosynthetic Link Leading to the Hetidine and Arcutine C20-Diterpenoid Alkaloids or an Oxidative Degradation Product?

ABSTRACT: A possible biosynthetic link between atropurpuran, the hetidine diterpenoid alkaloids and the alkaloid arcutine and congeners is proposed. The feasibility of aspects of this biosynthesis, especially key 1,2-rearrangements, have been examined computationally.

SUBMITTER: Weber M 

PROVIDER: S-EPMC4445844 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Atropurpuran - Missing Biosynthetic Link Leading to the Hetidine and Arcutine C<sub>20</sub>-Diterpenoid Alkaloids or an Oxidative Degradation Product?

Weber Manuel M   Owens Kyle K   Sarpong Richmond R  

Tetrahedron letters 20150601 23

A possible biosynthetic link between atropurpuran, the hetidine diterpenoid alkaloids and the alkaloid arcutine and congeners is proposed. The feasibility of aspects of this biosynthesis, especially key 1,2-rearrangements, have been examined computationally. ...[more]

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