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Crystal structure of [butane-2,3-dione bis-(4-methyl-thio-semicarbazonato)-?(4) S,N (1),N (1'),S'](pyridine-?N)zinc(II).

ABSTRACT: In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the Zn(II) ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490?Å from the plane of best fit defined by the bis-(thio-semicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular N-H?N and N-H?S hydrogen-bonding interactions extend parallel to [10-1].

SUBMITTER: Brown OC

PROVIDER: S-EPMC4645023 | biostudies-literature | 2015 Nov

REPOSITORIES: biostudies-literature

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Crystal structure of [butane-2,3-dione bis-(4-methyl-thio-semicarbazonato)-κ(4) S,N (1),N (1'),S'](pyridine-κN)zinc(II).

Brown Oliver C OC Tocher Derek A DA Blower Philip J PJ Went Michael J MJ

Acta crystallographica. Section E, Crystallographic communications 20151017 Pt 11

In the structure of the title complex, [Zn(C8H14N6S2)(C5H5N)], the Zn(II) ion has a pseudo-square-pyramidal coordination environment and is displaced by 0.490 Å from the plane of best fit defined by the bis-(thio-semicarbazonate) N2S2 donor atoms. Chains sustained by intermolecular N-H⋯N and N-H⋯S hydrogen-bonding interactions extend parallel to [10-1]. ...[more]

PMID: 26594508

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