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Bis(ferrocenecarbaldehyde 4-methyl-thio-semicarbazonato-κN,S)zinc(II) methanol solvate.

ABSTRACT: In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(8)H(9)N(3)S)(2)]·CH(3)OH, the dihedral angles between the substituted and unsubstituted cyclo-penta-dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn(II) atom at the flap. Each methanol solvent mol-ecule is linked to three ferrocene groups via inter-molecular O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds. The crystal structure is further consolidated by C-H⋯π inter-actions.

SUBMITTER: Vikneswaran MR

PROVIDER: S-EPMC2969868 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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Bis(ferrocenecarbaldehyde 4-methyl-thio-semicarbazonato-κN,S)zinc(II) methanol solvate.

Vikneswaran M R MR Teoh Siang Guan SG Quah Ching Kheng CK Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20090808 Pt 9

In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(8)H(9)N(3)S)(2)]·CH(3)OH, the dihedral angles between the substituted and unsubstituted cyclo-penta-dienyl rings are 89.34 (8) and 85.73 (9)°, respectively. The two Zn/S/C/N/N five-membered rings adopt envelope conformations, with the Zn(II) atom at the flap. Each methanol solvent mol-ecule is linked to three ferrocene groups via inter-molecular O-H⋯N, N-H⋯O and C-H⋯O hydrogen bonds. The crystal structure is further consolidated by C-H⋯π inter-actio ...[more]

PMID: 21577394

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