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Surface-Amorphous and Oxygen-Deficient Li3VO4-δ as a Promising Anode Material for Lithium-Ion Batteries.


ABSTRACT: Surface-amorphous and oxygen-deficient Li3VO4-δsynthesized by simple annealing of Li3VO4 powders in a vacuum shows great enhancements in both reversible capacity and coulombic efficiency for the first discharge/charge without delicate size control and carbon coating. The results are associated with the improved charge-transfer kinetics caused by the amorphous surface of Li3VO4-δ .

SUBMITTER: Chen L 

PROVIDER: S-EPMC5033021 | biostudies-literature | 2015 Sep

REPOSITORIES: biostudies-literature

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Surface-Amorphous and Oxygen-Deficient Li<sub>3</sub>VO<sub>4-<i>δ</i></sub> as a Promising Anode Material for Lithium-Ion Batteries.

Chen Liang L   Jiang Xiaolei X   Wang Nana N   Yue Jie J   Qian Yitai Y   Yang Jian J  

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20150610 9


<b>Surface-amorphous and oxygen-deficient Li<sub>3</sub>VO<sub>4-<i>δ</i></sub></b><b>synthesized by simple annealing of Li<sub>3</sub>VO<sub>4</sub> powders in a vacuum</b> shows great enhancements in both reversible capacity and coulombic efficiency for the first discharge/charge without delicate size control and carbon coating. The results are associated with the improved charge-transfer kinetics caused by the amorphous surface of Li<sub>3</sub>VO<sub>4-<i>δ</i></sub> . ...[more]

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