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Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts.

ABSTRACT: The radical carbohydroxylation of styrenes with aryldiazonium salts has been achieved under mild thermal conditions. A broad range of aryldiazonium salts was tolerated, and the reaction principle based on a radical-polar crossover mechanism could be extended to carboetherification as well as to a two-step, metal-free variant of the Meerwein arylation leading to stilbenes.

SUBMITTER: Kindt S

PROVIDER: S-EPMC5089591 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature

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Thermally Induced Carbohydroxylation of Styrenes with Aryldiazonium Salts.

Kindt Stephanie S Wicht Karina K Heinrich Markus R MR

Angewandte Chemie (International ed. in English) 20160608 30

The radical carbohydroxylation of styrenes with aryldiazonium salts has been achieved under mild thermal conditions. A broad range of aryldiazonium salts was tolerated, and the reaction principle based on a radical-polar crossover mechanism could be extended to carboetherification as well as to a two-step, metal-free variant of the Meerwein arylation leading to stilbenes. ...[more]

PMID: 27273583

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