Stable porphyrin Zr and Hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses.
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ABSTRACT:
SUBMITTER: Zheng J
PROVIDER: S-EPMC5492870 | biostudies-literature | 2015 Jun
REPOSITORIES: biostudies-literature
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Stable porphyrin Zr and Hf metal-organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses.
Zheng Jun J Wu Mingyan M Jiang Feilong F Su Weiping W Hong Maochun M
Chemical science 20150331 6
Two isostructural porphyrin Zr and Hf metal-organic frameworks (<b>FJI-H6</b> and <b>FJI-H7</b>) are rationally synthesized, and are constructed from 2.5 nm cubic cages. Notably, they both possess high water and chemical stability and can undergo single-crystal to single-crystal transformations to embed Cu<sup>2+</sup> ions into the open porphyrin rings. <b>FJI-H6</b> has a high BET surface area of 5033 m<sup>2</sup> g<sup>-1</sup>. Additionally, they exhibit promising catalytic abilities to con ...[more]
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