Coordination compounds containing bis-di-thiol-ene-chelated molybdenum(IV) and oxalate: comparison of terminal with bridging oxalate.

ABSTRACT: Two coordination compounds containing tetra-n-butyl-ammonium cations and bis-tfd-chelated molybdenum(IV) [tfd^2- = S₂C₂(CF₃)₂^2-] and oxalate (ox^2-, C₂O₄^2-) in complex anions are reported, namely bis-(tetra-n-butyl-ammonium) bis-(1,1,1,4,4,4-hexa-fluoro-but-2-ene-2,3-di-thiol-ato)oxalatomolybdate(IV)-chloro-form-oxalic acid (1/1/1), (C₁₆H₃₆N)₂[Mo(C₄F₆S₂)₂(C₂O₄)]·CHCl₃·C₂H₂O₄ or (N ⁿ Bu₄)₂[Mo(tfd)₂(ox)]·CHCl₃·C₂H₂O₄, and bis-(tetra-n<

SUBMITTER: Gapinska A 

PROVIDER: S-EPMC5598849 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature