Nickel-Catalyzed Enantioselective Conjunctive Cross-Coupling of 9-BBN Borates.

ABSTRACT: Catalytic enantioselective conjunctive cross-coupling between 9-BBN borate complexes and aryl electrophiles can be accomplished with Ni salts in the presence of a chiral diamine ligand. The reactions furnish chiral 9-BBN derivatives in an enantioselective fashion and these are converted to chiral alcohols and amines, or engaged in other stereospecific C-C bond forming reactions.

SUBMITTER: Chierchia M 

PROVIDER: S-EPMC5699474 | biostudies-literature | 2017 Sep

REPOSITORIES: biostudies-literature