Local Moment Instability of Os in Honeycomb Li_2.15Os_0.85O₃.

ABSTRACT: Compounds with honeycomb structures occupied by strong spin orbit coupled (SOC) moments are considered to be candidate Kitaev quantum spin liquids. Here we present the first example of Os on a honeycomb structure, Li_2.15(3)Os_0.85(3)O₃ (C2/c, a = 5.09 Å, b = 8.81 Å, c = 9.83 Å, β = 99.3°). Neutron diffraction shows large site disorder in the honeycomb layer and X-ray absorption spectroscopy indicates a valence state of Os (4.7 ± 0.2), consistent with the nominal concentration. We observe a transport band gap of Δ = 243 ± 23 meV, a large van Vleck susceptibility, and an effective moment of 0.85 μ_B, much lower than expected from 70% Os(+5). No evidence of long range order is found above 0.10 K but a spin glass-like peak in ac-susceptibility is obser

SUBMITTER: Wallace MK 

PROVIDER: S-EPMC5919924 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature