Room temperature olefination of methane with titanium-carbon multiple bonds.

ABSTRACT: C-H activation of methane followed by dehydrocoupling at room temperature led ultimately to the formation of the olefin H₂C[double bond, length as m-dash]CH ^t Bu via the addition of redox-active ligands (L) such as thioxanthone or 2,2'-bipyridine (bipy) to (PNP)Ti[double bond, length as m-dash]CH ^t Bu(CH₃) (1). Using both of these exogenous ligand systems, we could trap the titanium fragment via an insertion reaction with these two substrates to afford species of the type (PNP)Ti(L)(LH). A combination of computational and isotopic labeling studies reveals that the L ligand promotes the C-C bond forming step by migration of the methyl moiety in 1 to the α-alkylidene carbon by producing a Ti(iii) species (P

SUBMITTER: Kurogi T 

PROVIDER: S-EPMC5933228 | biostudies-literature | 2018 Apr

REPOSITORIES: biostudies-literature