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Scalable Exfoliation of Bulk MoS₂ to Single- and Few-Layers Using Toroidal Taylor Vortices.


ABSTRACT: The production of a large amount of high-quality transition metal dichalcogenides is critical for their use in industrial applications. Here, we demonstrate the scalable exfoliation of bulk molybdenum disulfide (MoS₂) powders into single- or few-layer nanosheets using the Taylor-Couette flow. The toroidal Taylor vortices generated in the Taylor-Couette flow provide efficient mixing and high shear stresses on the surfaces of materials, resulting in a more efficient exfoliation of the layered materials. The bulk MoS₂ powders dispersed in N-methyl-2-pyrrolidone (NMP) were exfoliated with the Taylor-Couette flow by varying the process parameters, including the initial concentration of MoS₂ in the NMP, rotation speed of the reactor, reaction time, and temperature. With a batch process at an opt

SUBMITTER: Kaushik V 

PROVIDER: S-EPMC6116258 | biostudies-literature | 2018 Aug

REPOSITORIES: biostudies-literature