Insights into the excited state dynamics of Fe(ii) polypyridyl complexes from variable-temperature ultrafast spectroscopy.

ABSTRACT: In an effort to better define the nature of the nuclear coordinate associated with excited state dynamics in first-row transition metal-based chromophores, variable-temperature ultrafast time-resolved absorption spectroscopy has been used to determine activation parameters associated with ground state recovery dynamics in a series of low-spin Fe(ii) polypyridyl complexes. Our results establish that high-spin (⁵T₂) to low-spin (¹A₁) conversion in complexes of the form [Fe(4,4'-di-R-2,2'-bpy')₃]²⁺ (R = H, CH₃, or tert-butyl) is characterized by a small but nevertheless non-zero barrier in the range of 300-350 cm^-1 in fluid CH₃CN solution, a value that more than doubles to ∼750 cm^-1<

SUBMITTER: Carey MC 

PROVIDER: S-EPMC6335846 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature