Ontology highlight
ABSTRACT:
SUBMITTER: Chicharro DV
PROVIDER: S-EPMC6610558 | biostudies-literature | 2019 Jul
REPOSITORIES: biostudies-literature
Chicharro David V DV Poullain Sonia Marggi SM Zanchet Alexandre A Bouallagui Aymen A García-Vela Alberto A Senent María L ML Rubio-Lago Luis L Bañares Luis L
Chemical science 20190522 26
The photochemistry of the ethyl radical following excitation to the 3p Rydberg state is investigated in a joint experimental and theoretical study. Velocity map images for hydrogen atoms detected from photoexcited isotopologues CH<sub>3</sub>CH<sub>2</sub>, CH<sub>3</sub>CD<sub>2</sub> and CD<sub>3</sub>CH<sub>2</sub> at ∼201 nm, are discussed along with high-level <i>ab initio</i> electronic structure calculations of potential energy curves and non-adiabatic coupling matrix elements (NACME). A ...[more]