Unknown

Dataset Information

0

An Old Dog with New Tricks - Additions to the Cesium Lithium Chloride System: Cs3Li2Cl5 and the Hydrated Cs3LiCl4 · 4H2O.

ABSTRACT: The CsCl/LiCl system has been studied for over a century now. Numerous phases have been predicted - only three have hitherto been found. We present the synthesis and single-crystal structure of the cesium lithium pentachloride Cs3Li2Cl5, predicted earlier but with a different structure. The anhydrous new phase readily reacts to Cs3LiCl4 · 4H2O in air. The tetrahydrate can also be obtained through the simplest, most inexpensive and green synthesis possible: an immediate, room-temperature mechanosynthesis from only CsCl and LiCl (3 : 1) in air. Differential scanning calorimetry (DSC) and thermogravimetric analyses (TGA), as well as in situ temperature-dependent powder X-ray diffraction studies on this second ever reported ternary alkali chloride hydrate allowed for a revision of the CsCl/LiCl phase diagram. Density of states and total energy calculations further elucidate the new alkali chlorides and update the relative stability of previous structure predictions.

SUBMITTER: Ortner TS 

PROVIDER: S-EPMC6733704 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

An Old Dog with New Tricks - Additions to the Cesium Lithium Chloride System: Cs<sub>3</sub>Li<sub>2</sub>Cl<sub>5</sub> and the Hydrated Cs<sub>3</sub>LiCl<sub>4</sub> · 4H<sub>2</sub>O.

Ortner Teresa S TS   Scheifers Jan P JP   Flores Justin J   Zhang Yuemei Y   Iyer Abishek K AK   Gesing Thorsten M TM   Fokwa Boniface P T BPT  

European journal of inorganic chemistry 20190719 30

The CsCl/LiCl system has been studied for over a century now. Numerous phases have been predicted - only three have hitherto been found. We present the synthesis and single-crystal structure of the cesium lithium pentachloride Cs<sub>3</sub>Li<sub>2</sub>Cl<sub>5</sub>, predicted earlier but with a different structure. The anhydrous new phase readily reacts to Cs<sub>3</sub>LiCl<sub>4</sub> · 4H<sub>2</sub>O in air. The tetrahydrate can also be obtained through the simplest, most inexpensive and  ...[more]

Similar Datasets

Unknown Halide Mixing and Phase Segregation in Cs<sub>2</sub>AgBiX<sub>6</sub> (X = Cl, Br, and I) Double Perovskites from Cesium-133 Solid-State NMR and Optical Spectroscopy.
| S-EPMC7558408 | biostudies-literature
Unknown Considerable matrix shift in the electronic transitions of helium-solvated cesium dimer cation Cs<sub>2</sub>He.
| S-EPMC7116336 | biostudies-literature
Unknown Two Mercury Antimony Chalcogenides Cs<sub>2</sub>HgSb<sub>4</sub>S<sub>8</sub> and Cs<sub>2</sub>Hg<sub>2</sub>Sb<sub>2</sub>Se<sub>6</sub> with Cesium Cations as Counterions.
| S-EPMC6643381 | biostudies-literature
Unknown Glassy thermal conductivity in Cs<sub>3</sub>Bi<sub>2</sub>I<sub>6</sub>Cl<sub>3</sub> single crystal.
| S-EPMC9420152 | biostudies-literature
Unknown Subarachnoid space: new tricks by an old dog.
| S-EPMC3365109 | biostudies-literature
Unknown Phototoxicity effects of NIR-irradiated cesium tungsten oxide (Cs<sub>0.33</sub>WO<sub>3</sub>) nanoparticles on zebrafish embryos: A direct immersion study.
| S-EPMC9743432 | biostudies-literature
Unknown Moisture-Assisted near-UV Emission Enhancement of Lead-Free Cs<sub>4</sub>CuIn<sub>2</sub>Cl<sub>12</sub> Double Perovskite Nanocrystals.
| S-EPMC8759080 | biostudies-literature
Unknown Cs[Cl<sub>3</sub> F<sub>10</sub> ]: A Propeller-Shaped [Cl<sub>3</sub> F<sub>10</sub> ]<sup>-</sup> Anion in a Peculiar A<sup>[5]</sup> B<sup>[5]</sup> Structure Type.
| S-EPMC7589245 | biostudies-literature
Unknown Versatile vapor phase deposition approach to cesium tin bromide materials CsSnBr<sub>3</sub>, CsSn<sub>2</sub>Br<sub>5</sub> and Cs<sub>2</sub>SnBr<sub>6</sub>.
| S-EPMC9055831 | biostudies-literature
Unknown Cs<sub>3</sub>Cu<sub>4</sub>In<sub>2</sub>Cl<sub>13</sub> Nanocrystals: A Perovskite-Related Structure with Inorganic Clusters at A Sites.
| S-EPMC7497414 | biostudies-literature